Serviços Personalizados
Journal
Artigo
Indicadores
- Citado por SciELO
- Acessos
Links relacionados
- Similares em SciELO
Compartilhar
Ciência e Técnica Vitivinícola
versão impressa ISSN 0254-0223
Ciência Téc. Vitiv. v.24 n.1 Dois Portos 2009
Comparison of altyernative systems for the ageing of wine brandvy. Oxigenation and wood shape effect.
Sara Canas*, Ilda Caldeira, A. Pedro Belchior
INRB, L-INIA/Dois Portos, Quinta dAlmoinha, 2565-191 Dois Portos, Portugal
*Corresponding author: Tel.: +351 261712106; Fax: +351 261712426, E-mail: evn.sara.canas@mail.net4b.pt
(Manuscrito recebido em 07.05.09. Aceite para publicação em 28.05.09)
SUMMARY
During the first year of ageing, the dissolved oxygen, dry extract, total polyphenol index, low molecular weight compounds, colour parameters and sensory properties of wine brandies were analysed with regard to the kind of ageing system: 650-L wooden barrels (traditional system) and 40-L stainless-steel tanks with wood tablets, with and without oxygenation (alternative systems). The barrels and wood pieces were manufactured from Portuguese chestnut wood (Castanea sativa Mill.) with heavy toasting level. The quantity of tablets was calculated in order to reproduce the surface/volume ratio of a 650-L barrel. The oxygenation was made by the application of air with a specific device in the middle height of the tanks, after 60, 90, 120, 180 and 360 days of ageing. In the experimental conditions, the results obtained demonstrated that the chemical composition and the colour evolution of the wine aged brandies are closely dependent on the ageing system. The oxygen effect on the total polyphenol index and on the low molecular weight phenolic compounds found in the brandies aged in traditional and alternative systems is quite different. This aspect is of great importance since it is strongly related with the chemical changes that occur during the ageing process and determine the quality of the brandies. Contrary to what have been observed in the ageing of red wines, the oxygen consumption in the brandies aged in wooden barrels did not induced colour stabilization, suggesting that the chemical mechanisms and the compounds responsible for the colour changes of the brandy should be different from those identified in red wine.
Key-words: wine aged brandy, oxygenation, wood shape, physical and chemical characteristics.
RESUMO
Comparação de sistemas alternativos para o envelhecimento de aguardente vínica. Efeito da oxigenação e da forma da madeira.
Durante o primeiro ano de envelhecimento, procedeu-se à análise do oxigénio dissolvido, extracto seco, índice de polifenóis totais, compostos de massa molecular baixa, características cromáticas e sensoriais de aguardentes vínicas envelhecidas em diferentes sistemas: vasilhas de madeira de 650 L (sistema tradicional) e depósitos de aço inoxidável de 40 L com dominós de madeira, com e sem oxigenação (sistemas alternativos). As vasilhas e os dominós foram produzidos a partir de madeira de castanheiro português (Castanea sativa Mill.) com queima forte. A quantidade de dominós foi calculada de modo a reproduzir a relação superfície/volume de uma vasilha de 650 L. A oxigenação consistiu na aplicação de ar, através de equipamento específico, a meia altura dos depósitos, após 60, 90, 120, 180 e 360 dias de envelhecimento. Nas condições do ensaio, os resultados obtidos demonstram que a composição química e a evolução da cor das aguardentes vínicas envelhecidas são fortemente condicionadas pelo sistema de envelhecimento. O efeito do oxigénio no índice de polifenóis totais e nos compostos de massa molecular baixa das aguardentes envelhecidas nos sistemas tradicional e alternativos é consideravelmente diferente. Este aspecto assume considerável importância, na medida em que se encontra estreitamente relacionado com as alterações químicas que ocorrem durante o processo de envelhecimento e que determinam a qualidade da aguardente. Contrariamente ao que tem sido observado no envelhecimento de vinhos tintos, o consumo de oxigénio não induziu a estabilização da cor nas aguardentes envelhecidas durante um ano em vasilhas de madeira. Este facto sugere que os mecanismos químicos e os compostos envolvidos nas alterações cromáticas da aguardente devem ser diferentes dos que têm sido identificados no vinho tinto.
Palavras-chave: aguardente vínica envelhecida, oxigenação, forma da madeira, características físico-químicas.
Full text only available in PDF format.
Texto completo disponível apenas em PDF.
REFERENCES
Alcalde-Eon C., Escribano-Bailón M.T., Santos-Buelga C., Rivas-Gonzalo J.C., 2006. Changes in the detailed pigment composition of red wine durting maturity and ageing. A comprehensive study. Anal. Chim. Acta, 563, 238-254.
Arapitsas P., Antonopoulos A., Stefanou E., Dourtoglou V.G., 2004. Artificial aging of wines using oak chips. Food Chem., 86, 563 570.
Asenstorfer R.E., Hayasaka Y, Jones G.P., 2001. Isolations and structures of oligomeric wine pigments by bisulfite-mediated ion exchange chromatography. J. Agric. Food Chem., 49, 5957-5963.
Atanasova V., Fulcrand H., Cheynier V., Moutounet M., 2002. Effect of oxygenation on polyphenol changes occurring in the course of wine-making. Anal. Chim. Acta, 458, 15-27.
Belchior A.P., Almeida T.G.T., Mateus A.M., Canas S., 2003. Ensaio laboratorial sobre a cinética de extracção de compostos de baixa massa molecular da madeira pela aguardente. Ciência e Téc. Vitiv., 18, 29-41. [ Links ]
Belchior A.P., Caldeira I., Costa S., Tralhão G., Ferrão A., Mateus A.M., Carvalho E., 2001. Evolução das características fisicoquímicas e organolépticas de aguardentes Lourinhã ao longo de cinco anos de envelhecimento em madeira de carvalho e de castanheiro. Ciência e Téc. Vitiv., 16, 81-94. [ Links ]
Belchior A.P., Mateus A.M., Soares A.M., 2005. Comparação do envelhecimento de aguardente Lourinhã em vasilhas de madeiras de castanheiro e de carvalho e em dois volumes. Ciência e Téc. Vitiv., 20, 91-103. [ Links ]
Belchior A. P., San-Romão V., 1982. Influence de loxygène et de la lumière sur lévolution de la composition phénolique des eauxde-vie vieillis en bois de chêne. Bull. Liasion Groupe Polyphenols, 11, 598-604.
Caldeira I., Belchior A.P., Clímaco M.C., Bruno de Sousa R., 2002. Aroma profiles of Portuguese brandies aged in chestnut and oak woods. Anal. Chim. Acta, 458, 55-62.
Caldeira I., Canas S., Costa S., Carvalho E., Belchior A.P., 1999. Formação de uma câmara de prova organoléptica de aguardentes velhas e selecção de descritores sensoriais. Ciência e Téc. Vitiv., 14, 21-30. [ Links ]
Caldeira I., Clímaco M.C., Bruno de Sousa R., Belchior A.P., 2006b. Volatile composition of oak and chestnut woods used in brandy ageing: modification induced by heat treatment. J. Food Eng., 76, 202-211.
Caldeira I., Mateus A.M., Belchior A.P., 2006a. Flavour and odour profile modifications during the first five years of Lourinhã brandy maturation on different wooden barrels. Anal. Chim. Acta, 563, 264-273.
Canas S., Belchior A. P., Caldeira I., Spranger M.I., Bruno de Sousa R., 2000a. La couleur et son évolution dans les eaux-devie Lourinhã pendant les trois premières années du vieillissement. Ciência Tec. Vitiv., 15, 1-14. [ Links ]
Canas, S., Belchior A.P., Falcão, A., Gonçalves, J.A., Spranger, M.I., Bruno de Sousa, R., 2007. Effect of heat treatment on the thermal and chemical modifications of oak and chestnut wood used in brandy ageing. Ciência Tec. Vitiv., 22, 5-14. [ Links ]
Canas, S., Belchior, A.P., Spranger, M.I., Bruno de Sousa, R., 2003. High-performance liquid chromatography method for analysis of phenolic acids, phenolic aldehydes and furanic derivatives in brandies. Development and validation. J. Sep. Sci., 26, 496-502.
Canas S., Belchior A.P., Spranger M.I., Bruno-de-Sousa R., 2004b. Extracção e difusão dos compostos de massa molecular baixa da madeira ao longo do primeiro ano de envelhecimento de uma aguardente Lourinhã. In: Actas do 6º Simpósio de Vitivinicultura do Alentejo, Vol. 2, 121-128.
Canas S., Caldeira I., Leandro M.C., Spranger M.I., Climaco M.C., Belchior A.P., 1998. Phenolic compounds in a Lourinhã brandy extracted from different woods. In: Polyphenols Communications 98, Vol. 2, 373-374.
Canas S., Caldeira I., Mateus A.M., Belchior A. P., Clímaco M.C., Bruno de Sousa R., 2006. Effect of natural seasoning on the chemical composition of chestnut wood used for barrel making. Ciência Tec. Vitiv., 21, 1-16. [ Links ]
Canas S., Grazina N., Spranger M.I., Belchior A.P., 2000c. Modelisation of heat treatment of Portuguese oak wood (Quercus pyrenaica Willd.). Analysis of the behaviour of low molecular weight phenolic compounds. Ciência Tec. Vitiv., 15, 75-94. [ Links ]
Canas, S., Leandro, M.C., Spranger, M.I., Belchior, A.P., 1999. Low molecular weight organic compounds of chestnut wood (Castanea sativa L.) and corresponding aged brandies. J. Agric. Food Chem., 47, 5023-5030.
Canas S., Leandro M.C., Spranger M.I., Belchior A.P., 2000b. Influence of botanical species and geographical origin on the content of low molecular weight phenolic compounds of woods used in Portuguese cooperage. Holzforschung, 54, 255-261.
Canas S., Spranger M. I., Belchior A. P., Bruno-de-Sousa R., 2004a. Isolation and identification by LC-ESI-MS of hydrolyzable tannins from Quercus pyrenaica Willd. and Castanea sativa Mill. th heartwoods. In: Abstracts of the 4 Tannin Conference, P8.
Canas, S., Vaz, M., Belchior, A.P., 2008. Influence de la dimension du fût dans les cinétiques dextraction/oxydation des composés phénoliques du bois pour les eaux-de-vie Lourinhã. In: Les eauxde-vie traditionnelles dorigine viticole. 143-146. Bertrand A. (ed.), Lavoisier - Tec & Doc, Paris.
Cano-López M., Pardo-Minguez F., López-Roca J.M., Gómez-Plaza E., 2006. Effect of microoxygenation on anthocyanins and derived pigment content and chromatic characteristics of red wines. Am. J. Enol. Vit., 57, 325-331.
Cantagrel R., Mazerrolles G., Vidal J.P., Galy B., 1991. Evolution analytique et organoleptique des eaux-de-vie de cognac au cours du vieillissement. 1ère partie: incidence des techniques de tonnelleries. In: Les eaux-de-vie traditionnelles dorigine viticole. 567-572. Bertrand A. (ed.), Lavoisier - Tec & Doc, Paris.
del Álamo M., Nevares I., Gallego L., Martin C., Merino S., 2008. Aging markers from bottled red wine aged with chips, staves and barrels. Anal. Chim. Acta, 621, 86-99.
Eiriz N., Santos-Oliveira J.F., Clímaco M.C., 2007. Fragmentos de madeira de carvalho no estágio de vinhos tintos. Ciência Tec. Vitiv., 22, 63-71. [ Links ]
Es-Safi N., Cheynier V., Moutounet M., 2000. Study of the reactions between (+)-catechin and furfural derivatives in the presence or absence of anthocyanins and their implication in food color change. J. Agric. Food Chem., 48, 5946-5954.
Frangipane M.T., De Santis D., Ceccarelli A., 2007. Influence of oak woods of different geographical origins on quality of wines aged in barriques and using oak chips. Food Chem., 103, 46-54
Hale M.D., McCafferty K., Larmie E., Newton J., Swan J.S., 1999. The influence of oak seasoning and toasting parameters on the composition and quality of wine. Am. J. Enol. Vitic., 50, 495 502.
Herve du Penhoat C.L.M., Michon V.M.F., Peng S., Viriot C., Scalbert A., Gage D., 1991. Structural elucidation of new dimeric ellagitannins from Quercus robur L. Roburins A-E. J. Chem. Soc. Perkin Trans., I, 1653-1660.
Joseph E., Marché M., 1972. Contribution à létude du vieillissement du Cognac. Identification de la scopolétine, de laesculétine, de lombelliférone, de la ß-méthyl-ombelliférone, de l?aesculine et de la scopoline, hétérosides provenant du bois. Conn. Vigne Vin, 6, 1-58.
Kelly M., Wollan D., 2003. Micro-oxygenation of wine in barrels. Aust. & N. Z. Grap. Wine, Annual Technical Issue, 45-50.
Llaudy M.C., Canals R., González-Manzano S., Canals J.M., Santos-Buelga C., Zamora F., 2006. Influence of micro-oxygenation treatment before oak aging on phenolic compounds composition, astringency, and color of red wine. J. Agric. Food Chem., 54, 4246-4252.
Marco J., Artajona J., Larremi M. S., Rius F. X., 1994. Relationship between geographical origin and chemical composition of wood for oak barrels. Am. J. Enol. Vit., 45, 192-200.
Mateus N., Carvalho E., Carvalho A.R.F., Melo A., González-Paramás A.M., Santos-Buelga C., Silva A.M.S., Freitas V., 2003a. Isolation and structural characterization of new acylated anthocyanin-vinyl-flavanol pigments occurring in aging red wines. J. Agric. Food Chem., 51, 277-282.
Mateus N., Freitas V., 2001. Evolution and stability of anthocyanin-derived pigments during Port wine aging. J. Agr. Food Chem., 49, 5217-5222.
Mateus N., Silva A.M.S., Rivas-Gonzalo J.C., Santos-Buelga C., Freitas V., 2003b. A new class of blue anthocyanin-derived pigments isolated from red wines. J. Agric. Food Chem., 51, 19191923.
Mateus N., Silva A.M.S., Santos-Buelga C., Rivas-Gonzalo J.C., Freitas V., 2002. Identification of anthocyanin-flavanol pigments in red wines by NMR and mass spectrometry. J. Agric. Food Chem., 50, 2110-2116.
Mourgues J., Jouret C., Moutounet M., 1973. Détermination du taux doxygène dissous et du potentiel oxydo-réducteur des eauxde-vie darmagnac au cours de leur maturation. Ann. Technol. Agric., 22, 75-90.
Moutounet M., Mazauric J.P., Saint-Pierre B., Hanocq J.F., 1998. Gaseous exchange in wines stored in barrels. J. Sci. Tech. Tonnellerie, 4, 115-129.
Nevares I., del Álamo M., 2008. Measurements of dissolved oxygen during red wines tank aging with chips and micro-oxygenation. Anal. Chim. Acta, 621, 68-78.
Nikfardjam M.P., Dykes S., 2003. Micro-Oxygenation research at Lincoln University. Part 3. Polyphenolic analysis of Cabernet Sauvignon wine under the application of micro-oxygenation. Aust. & N. Z. Grap. Wine, 41-44.
OIV, 1994. Recueil des méthodes internationales danalyse des boissons spiritueuses, des alcools et de la fraction aromatique des boissons, 311 p., OIV, Paris.
Parish M., Wollan D., Paul R., 2000. Micro-oxygenation - A review. Aust. & N. Z. Grap. Wine, Annual Technical Issue, 47-50.
Patrício I., Canas S., Belchior A.P., 2005. Effect of brandies agitation on the kinetics of extraction/oxidation and diffusion of wood extractable compounds in experimental model. Ciência Tec. Vitiv., 20, 1-15 [ Links ]
Prida A., Puech J.L., 2006. Influence of geographical origin and botanical species on the content of extractives in American, French, and East European oak woods. J. Agric. Food Chem., 54, 8115-8126.
Puech J.-L., Jouret C., Goffinet B., 1985. Évolution des composés phénoliques du bois de chêne au cours du vieillissement de larmagnac. Sci. Alim, 5, 379-392.
Rabier Ph., Moutounet M., 1991. Evolution dextractibles de bois de chêne dans une eau-de-vie de vin. Incidence du thermotraitement des barriques. In: Les eaux-de-vie traditionnelles dorigine viticole. 220-230. Bertrand, A. (ed.), Lavoisier - Tec & Doc, Paris.
Ribéreau-Gayon, P., 1970. Le dosage des composés phénoliques totaux dans les vins rouges. Chimique Analytique, 52, 627-631.
Sanza M.A., Domínguez I.N., Cárcel L.M.C., Gracia L.N., 2004. Analysis for low molecular weight phenolic compounds in a red wine aged in oak chips. Anal. Chim. Acta, 513, 229-237.
Sarni F., Moutounet M., Puech J.-L., Rabier Ph., 1990. Effect of heat treatment of oak wood extractable compounds. Holzforschung, 44, 461-466.
Sartini E., Arfelli G., Fabiani A., Piva A., 2007. Influence of chips, lees and micro-oxygenation during aging on the phenolic composition of a Sangiovese wine. Food Chem., 104, 1599-1604.
Snakkers G., Nepveu G., Guilley, Cantagrel R., 2000. Variabilités géographique, sylvicole et individuelle de la teneur en extractibles de chênes sessiles français (Quercus petraea Liebl.): polyphénols, octalactones et phénols volatils. Ann. For. Sci., 57, 251-260.
Sun B., Barradas T., Santos C., Leandro C., Spranger I., 2008. Formation of new stable pigments from condensation reaction between malvidin 3-glucoside and (-)-epicatechin mediated by acetaldehyde: Effect of tartaric acid concentration. Food Chem., 110, 344-351.
Sun B.S., Santos C.P.R., Leandro M.C., De Freitas V., Spranger M.I., 2007. High-performance liquid chromatography/electrospray ionization mass spectrometric characterization of new products formed by the reaction between flavanols and malvidin 3-glucoside in the presence of acetaldehyde. Rapid Communications in Mass Spectrometry, 21, 1-10.
Timberlake C.F., Bridle P., 1976. Interactions between anthocyanins, phenolic compounds, and acetaldehyde and their significance in red wines. Am. J. Enol. Vit., 27, 97-105.
Viriot, C., Scalbert, A., Lapierre, C., Moutounet, M., 1993. Ellagitannins and lignins in aging of spirits in oak barrels. J. Agric. Food Chem., 41, 1872-1879.