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Portugaliae Electrochimica Acta
Print version ISSN 0872-1904
Abstract
MOLINA, Angela; LOPEZ-TENES, Manuela; MORENO, Marién M. and SERNA, Carmen. Multistep Electrode Processes in Double Potential Step Techniques. Port. Electrochim. Acta [online]. 2003, vol.21, n.4, pp.345-359. ISSN 0872-1904.
A rigorous analytical solution for linear diffusion corresponding to the double potential step problem for a reversible multistep process is derived. The expressions obtained are valid for any value of the formal potentials of each step and can be applied to any double pulse technique without restriction on the duration of both pulses. Differential pulse techniques are applied to the study of reversible processes with different number of steps.
Keywords : reversible multistep electrode processes; double potential step techniques; planar electrodes.