Resumo

DOMINGUEZ-CRESPO, M.A. et al. Synthesis by Sol-gel Route and Characterization of Ceria Doped Silica Coatings on Commercial Carbon Steel. Port. Electrochim. Acta [online]. 2009, vol.27, n.3, pp.257-267. ISSN 0872-1904.

The use of silane formulations for the pre-treatment of metallic substrates prior to painting or as topcoat has been increasing during the recent years. The proposed formulations are very attractive because they present environmental friendliness, enhance adhesion properties and provide a barrier layer that delays the corrosion processes. One of the most used techniques to synthesized based-SiO₂ coatings is sol-gel. The preparation of sol-gel coatings with specific chemical functions offers potential advantages over traditional methods as it offers tailoring of their structure, texture and thickness and allows the fabrication of large coatings. The present work investigates the electrochemical behaviour of commercial carbon steel coated with ceria doped SiO₂ by sol-gel process in basic media. To evaluate the influence of temperature on adhesion and protective properties, the coatings were sintered at three different temperatures, 623 K, 723 K and 873 K, for 3 h. The anticorrosion behaviour, of the films has been characterized in an aggressive medium by electrochemical techniques, while structural characteristics and morphology was followed by X-Ray Diffraction, Fourier Transformed Infra-Red and Scanning Electron Microscopy techniques. The results indicated that the thin films act as a protective barrier against exposure to the corrosive medium (3.5 wt-% NaCl solution) and increase the lifetime of the susbtrate.

Palavras-chave : sol-gel process; SiO₂ coatings; structural characterization; rare earths; corrosion prevention.

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