Abstract

EDDY, N.O.; ODOEMELAM, S.A.; OGOKO, E.C.  and  ITA, B.I.. Inhibition of the Corrosion of Zinc in 0.01 - 0.04 M H₂SO₄ by Erythromycin. Port. Electrochim. Acta [online]. 2010, vol.28, n.1, pp.15-26. ISSN 0872-1904.

Inhibition of the corrosion of zinc in 0.01 to 0.0 4 M H₂SO₄ by erythromycin was studied using weight loss and hydrogen evolution methods. The results obtained indicate that erythromycin is a good adsorption inhibitor for the corrosion of zinc in H₂SO₄ solutions. The inhibition efficiency of erythromycin increases with increasing concentration but decreases with increase in temperature. Thermodynamic and adsorption studies reveal that the adsorption of erythromycin on zinc surface is exothermic, spontaneous and is characterised with increasing degree of orderliness. The adsorption characteristics of the inhibitor are best described by the Langmuir adsorption model. From the variation of inhibition efficiency with temperature and the calculated values of the activation and free energies (which are within the limits expected for physical adsorption), we propose that the adsorption of erythromycin on zinc surface is consistent with the mechanism of physical adsorption.

Keywords : corrosion inhibition; Zn, H₂SO₄; erythromycin.

        · text in English     · English ( pdf )