Abstract

MACA, Josef; FRK, Martin; ROZSIVALOVA, Zdenka  and  SEDLARIKOVA, Marie. Properties of Sulfolane Based Aprotic Electrolytes. Port. Electrochim. Acta [online]. 2013, vol.31, n.6, pp.321-330. ISSN 0872-1904.  https://doi.org/10.4152/pea.201306321.

The article deals with description of rheological and electrical properties of solvents for electrolytes of lithium-ion batteries. Solvents mixture of dimethyl sulfone and sulfolane at different volume ratios and with a lithium salt (LiClO₄) appears as a potentially suitable electrolyte. In this work, we investigate the influence of different solvents and their mixtures in order to find a solvent which increases the fire safety of such battery. The aim of this experiment is to investigate the rheological properties, particularly density and dynamic viscosity of solvents with lithium salt in temperature dependence and to find the optimal composition of the electrolyte from the perspective of achieving the lowest dynamic viscosity and better electrical conductivity, because both quantities are closely related with Walden's rule. The vibration method is used to determine the values of dynamic viscosity.

Keywords : electrolytes; solvents; viscosity; density.

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