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Portugaliae Electrochimica Acta

versão impressa ISSN 0872-1904

Resumo

VIJAYARANI, K.; DEVAN, M. Vishnu  e  NATARAJAN, R.. Effects of Addition of Alkaline Earth Metal-Beryllium on the Dissolution Behaviour of Aluminium-Zinc Alloy. Port. Electrochim. Acta [online]. 2017, vol.35, n.2, pp.91-102. ISSN 0872-1904.  https://doi.org/10.4152/pea.201702091.

This work has investigated the effect of addition of the Be alkaline earth metal on the dissolution behaviour of the Al-Zn alloy anode. Corrosion experiments were mounted to determine the optimal effect of an alkaline earth metal on the efficiencies of the aluminium alloy anodes. The corroded and unexposed sample surfaces were subject to microstructural characterization by using scanning electron microscopy and X-ray diffraction techniques. Al-Zn alloy doped with 1-5% by weight of beryllium was prepared to determine the effect on the anode efficiency in chloride environment. The different microstructure of the evolved Al-Zn alloy was correlated with the anode efficiencies. The obtained results showed that the anode efficiency of the Al-Zn alloy increased with the beryllium incorporation concentration. Al-Zn-Be-3% exhibits the better performance in terms of anode efficiency. The microstructure of the Al-Zn-Be alloy revealed increased distribution of beryllium globules and a breakdown of passive alumina film network on the anode surfaces, thus improving the anode efficiency.

Palavras-chave : corrosion; sacrificial anode; aluminium alloy; alkaline earth metal; efficiency; microstructures.

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