Portugaliae Electrochimica Acta
ISSN 0872-1904
LOVRIC, Milivoj KOMORSKY-LOVRIC, ebojka. Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode. []. , 38, 3, pp.165-174. ISSN 0872-1904. https://doi.org/10.4152/pea.202003165.
An irreversible electrode reaction influenced by the reversible potential dependent inhibition is theoretically analysed. The consequence of reactivation of the electrode surface is the continuation of electro-oxidation and the appearance of the second anodic peak in cyclic voltammetry. An indicator of the change of the electrode kinetics caused by the inhibitor is proposed.
: electrode reactivation; inhibition; partially blocked electrode; simulation.