Abstract

SINGH, Chitra; NEGI, Sujata; SINGH, Manpreeet  and  KISHORE, Kamal. Investigation on Conductance, Acoustical and Refractive Index Behavior of Stearalkonium Chloride in Methanol at 301 K. Port. Electrochim. Acta [online]. 2022, vol.40, n.1, pp.19-31.  Epub Feb 28, 2022. ISSN 0872-1904.  https://doi.org/10.4152/pea.2022400102.

Stearalkonium chloride (SAC) ultrasonic velocity has been measured in methanol, at 301 K temperature. Jacobson’s model has been used to evaluate adiabatic and molar compressibility, molar sound velocity, solvation number, relative association, relaxation strength and other acoustical constants. The results of ultrasonic measurements of different SAC solutions in methanol indicate that there is a signification interaction between SAC and methanol molecules in diluted solutions. The conductometric study indicates that SAC behaves as a weak electrolyte in methanol. The thermodynamic constants calculated from conductance measurements for SAC solutions in methanol depict that micellization is favored over dissociation processes. The refractive index variation with SAC solutions concentrations shows a marked change in the refractive index value at critical micelle concentrations (CMC). Data treatment of obtained ultrasonic velocity, conductance measurement and refractive index shows that there is significant interaction between SAC and methanol molecules in diluted solutions, and that SAC molecules do not aggregate appreciably below the CMC.

Keywords : Ultrasonic velocity; adiabatic compressibility and limiting molar conductance.

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