Inhibition Effects of Nitrones on the Corrosion of Mild Steel in Organic Acid Media

 

M. Thirumalaikumar* and S. Jegannathan

Department of Applied Chemistry, Sri Venkateswara College of Engineering, Pennalur, Sriperumbudur - 602105, India

 

DOI: 10.4152/pea.201101001

 

Abstract

Aromatic nitrones have been synthesized and investigated for their function as inhibitor for the corrosion of mild steel in the organic acid media – 20% formic acid and 20% acetic acid at various inhibitor concentrations in the range of 50 - 150 ppm. Weight loss measurements and potentio-dynamic polarization studies reveal that the nitrones behave as mixed type inhibitors. Among the nitrones tested, para-methyl substituted derivatives perform better as inhibitors than the un-substituted nitrones.

Keywords: corrosion inhibition, mild steel, adsorption, nitrones.

 

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References

1.      I.A. Sekine, A. Masuko, K. Senoo, Corrosion Sci. 43 (1987) 553.

2.      M.A. Quraishi, D. Jamal, Corrosion 56 (2000) 156. 10.5006/1.3280531

3.      V.B. Singh, R.N. Singh, Corrosion Sci. 37 (1995) 1399. 10.1016/0010-938X(95)00042-I

4.      I. Sekine, S. Hatakeyama, Y. Nakazawa, Corrosion. Sci. 27 (1987) 275. 10.1016/0010-938X(87)90023-0

5.      E. Heitz, Corrosion of Metals in Organic Solvents, Plenum Press, New York, NY, (1974) 226.

6.      I. Sekine, H. Ohkawa, T. Hank, Corrosion Sci. 22 (1982) 1113. 10.1016/0010-938X(82)90098-1

7.      I. Sekine, A. Chinda, Corrosion 40 (1984) 95.

8.      M.M. Singh and A. Gupta, Mater. Chem. Phys. 46 (1996) 15. 10.1016/0254-0584(96)80124-6

9.      M.Z.A. Rafiquee, S. Khan, N. Saxena, M.A. Quraishi, Port. Electrochim. Acta 25 (2007) 419. 10.4152/pea.200704419        [ Links ]

10.    S. Muralidharan, M.A. Quraishi, S.V.K. Iyer, Anti-Corr. Methods Mater. 44 (1997) 100. 10.1108/00035599710165342

11.    M.A. Quraishi, M.A.W. Khan, M. Ajmal, Anti-Corr. Methods Mater. 43 (1996) 5.

12.    B. Hammouti, A. Aouniti, M. Taleb, M. Bright, S. Kertit, Corrosion 51 (1995) 411. 10.5006/1.3293606

13.    A.-E. Nabey, E. Khammis, M. Sh. Ramadan, A.E. Gindy, Corrosion 52 (1996) 671. 10.5006/1.3292157

14.    M.M. Osman, R.A. El-Ghazawy, A.M. Al-Sabagli, Mater. Chem. Phys. 80 (2003) 55. 10.1016/S0254-0584(01)00588-0

15.    R. Hariharaputran, A. Subramanian, A.A. Antony, P. Manishankar, A. Gopalan, T. Vasudevan, S.V.K. Iyer, British Corrosion J. 33 (1998) 214.

16.    R. Hariharaputran, A. Subramanian, A.A. Antony, P. Manishankar, T. Vasudevan, S.V.K. Iyer, S. Anti- Corr. Methods Mater. 46 (1999) 35. 10.1108/00035599910252785

17.    S. Sivasubramanian, C. Amutha, M. Thirumalaikumar, S. Muthusubramanian, Indian J. Chem. 35(B) (1996) 503.

18.    M. Thirumalaikumar, S. Sivasubramanian, A. Ponnuswamy, P. Mohan, Eur. J. Med. Chem. 31 (1996) 905. 10.1016/S0223-5234(97)89854-6

19.    P. Merino, P. Padar, I. Delso, M. Thirumalaikumar, T. Tejero, L. Kovacs, Tetrahedron Lett. 47 (2006) 5013. 10.1016/j.tetlet.2006.05.114

20.    J. Hamer, A. Macaluso, Chem. Rev. 64 (1964) 473. 10.1021/cr60230a006

21.    N. Arumugam, P. Manisankar, S. Sivasubramanian, D.A. Wilson, Magn. Reson. Chem. 23 (1985) 246. 10.1002/mrc.1260230407

22.    S. Acharya, S.N. Upadhyay, Trans. Indian Inst. Met. 57 (2004) 297.

23.    M. Sahin, B. Bilgic, H. Yilmaz, Appl. Surf. Sci. 195 (2002) 1. 10.1016/S0169-4332(01)00783-8

24.    N. Hackerman, E.S. Snavely, J.S. Payne, J. Electrochem. Soc. 113 (1966) 677. 10.1149/1.2424089

25.    A.K. Dubey, G. Singh, Port. Electrochim. Acta 25 (2007) 205. 10.4152/pea.200702205

26.    S. Muralidharan, R. Chandrasekar, S.V.K Iyer, Proc. Indian. Acad. Sci. (Chem. Sci.) 112 (2000) 127.

 

Acknowledgement

The authors acknowledge the Principal, Sri Venkateswara College of Engineering, Pennalur, Sriperumbudur for constant encouragement and support provided to carry out this work and the Chief Scientific Officer and his associates, Technology Innovation Centre (SPIC) for the co-operation offered in carrying out the polarization studies.

 

* Corresponding author. E-mail address: mtkumar@svce.ac.in

Received 12 November 2009; accepted 2 February 2011