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Portugaliae Electrochimica Acta

Print version ISSN 0872-1904

Port. Electrochim. Acta vol.29 no.1 Coimbra  2011

 

Preparation and Physicochemical Characterization of Natural Phosphate and Kaolin Coatings in Stainless Steel

 

R. Najih,1 A. Chtaini2,* and H. Oulfajrite2

1 Laboratoire Valorisation et Sécurité des Produits Agro-Alimentaires, Faculté des Sciences et Techniques de Beni Mellal, Maroc

2 Equipe d’Electrochimie Moléculaire et Matériaux Inorganiques, Faculté des Sciences et Techniques de Beni Mellal, Maroc

 

DOI: 10.4152/pea.201101039

 

Abstract

The inhibition efficiency of natural phosphate and kaolin systems in controlling corrosion of stainless steel in HClO4 (0.1 M) solution has been evaluated by electrochemical polarization methods, and electrochemical impedance spectroscopy. The electrochemical data show that the corrosion resistance is greatly enhanced after surface modification. The best protection is obtained with natural phosphate. The uniform coatings of phosphate and kaolin on iron substrates were obtained by electro deposition.

Keywords: electrodeposition; natural phosphate; kaolin; impedance; polarization; stainless steel.

 

Full text only available in PDF format.

Texto completo disponível apenas em PDF.

 

References

1.      K.R. Adam, M. Antolovich, D.S. Baldwin, P.A. Duckworth, A.J. Leong, I.F. Lindoy, M.M.C. Partin, P.A. Tasker, J. Chem. Soc. Dalton Trans. 48 (1993) 1013. 10.1039/DT9930001013

2.      A.J. Blake, G.R. Reid, M. Schroder, J. Chem. Soc. Dalton Trans. 20 (1992) 2987. 10.1039/DT9920002987

3.      S. Helliarachi, Y.W. Chain, J. Chem. Technol. 2 (1995) 99.        [ Links ]

4.      K. Hnini, A. Tounsi, A. Chtaini, Bull. Electrochem. 21 (2005) 163-166.

5.      A. ElMhammedi, S. Fadel, A. Chtaini, Bull. Electrochem. 21 (2005) 445-449.

6.      A. ElMhammedi, L. Kinani, A. Chtaini, L.E. J. Practices and Technologies 11 (2007) 1-6.

7.      A guide to corrosion protection. Light Truck Frame Project Team., Michigan 1999.

8.      Natural phosphate comes from CERPHOS, Casablanca, Morocco.

9.      M.A. El Mhammedi, M. Bakasse, A. Chtaini, J. Hazardous Materials 145 (2007) 1. 10.1016/j.jhazmat.2007.02.054

10.    Kaolin comes Northeast of Douala country. Cameroun.

11.    Rapport de recherché de la Faculté des Sciences de l’Université de Yaoundé, Cameroun (2007).

 

* Corresponding author. E-mail address: chtainia@yahoo.fr

Received 7 September 2010; accepted 18 December 2010

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