<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>0870-8312</journal-id>
<journal-title><![CDATA[Ciência & Tecnologia dos Materiais]]></journal-title>
<abbrev-journal-title><![CDATA[C.Tecn. Mat.]]></abbrev-journal-title>
<issn>0870-8312</issn>
<publisher>
<publisher-name><![CDATA[Sociedade Portuguesa de Materiais]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S0870-83122006000100004</article-id>
<title-group>
<article-title xml:lang="en"><![CDATA[Tribological behaviour of reactive and co-sputtered W-S-C coatings]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Evaristo]]></surname>
<given-names><![CDATA[M.]]></given-names>
</name>
<xref ref-type="aff" rid="A01"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Nossa]]></surname>
<given-names><![CDATA[A.]]></given-names>
</name>
<xref ref-type="aff" rid="A02"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Cavaleiro]]></surname>
<given-names><![CDATA[A.]]></given-names>
</name>
<xref ref-type="aff" rid="A01"/>
</contrib>
</contrib-group>
<aff id="A01">
<institution><![CDATA[,Universidade de Coimbra Faculdade de Ciências e Tecnologia Centro de Investigação do Instituto de Ciências e Engenharia dos Materiais e Superfícies]]></institution>
<addr-line><![CDATA[Coimbra ]]></addr-line>
<country>Portugal</country>
</aff>
<aff id="A02">
<institution><![CDATA[,Instituto Politécnico da Guarda Escola Superior de Tecnologia e Gestão ]]></institution>
<addr-line><![CDATA[Guarda ]]></addr-line>
<country>Portugal</country>
</aff>
<pub-date pub-type="pub">
<day>00</day>
<month>01</month>
<year>2006</year>
</pub-date>
<pub-date pub-type="epub">
<day>00</day>
<month>01</month>
<year>2006</year>
</pub-date>
<volume>18</volume>
<numero>1-2</numero>
<fpage>21</fpage>
<lpage>26</lpage>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_arttext&amp;pid=S0870-83122006000100004&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_abstract&amp;pid=S0870-83122006000100004&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_pdf&amp;pid=S0870-83122006000100004&amp;lng=en&amp;nrm=iso"></self-uri><abstract abstract-type="short" xml:lang="en"><p><![CDATA[W-C-S films were deposited either by a reactive process in an Ar+CH4 atmosphere or by co-sputtering WS2 and C targets. The films were characterized concerning their chemical composition and mechanical properties. The results showed that the films, in both systems, have similar properties. Co-sputtered films are amorphous, whereas in the reactive process a gradual l oss of cristallinity is observed with the increase of C content in the films. The hardness and the adhesion are similar for both systems. The increase of C alloying to the films led to the improvement of both their hardness and adhesion. The tribological performance of the coatings was tested by ball-on-disk. The films deposited by co-sputtering present better results than the reactive deposited ones. With the increase of C content in these coatings an increase of the wear resistance is observed, reaching in the best case a wear coefficient of 3.1×10-16 m³/N×m. In the films deposited by reactive process, low wear coefficients can also be reached but no regular trend with increasing C contents can be observed.]]></p></abstract>
<kwd-group>
<kwd lng="en"><![CDATA[Tungsten disulfide]]></kwd>
<kwd lng="en"><![CDATA[WS2]]></kwd>
<kwd lng="en"><![CDATA[Friction coefficient]]></kwd>
<kwd lng="en"><![CDATA[Wear coefficient]]></kwd>
<kwd lng="en"><![CDATA[Self-lubricant]]></kwd>
</kwd-group>
</article-meta>
</front><body><![CDATA[ <p align="center"><b>Tribological behaviour of reactive and co-sputtered W-S-C    coatings</b></p>      <p>&nbsp;</p>      <p align="center">M. Evaristo <sup>(1)</sup>, A. Nossa <sup>(2)</sup>, A. Cavaleiro    <sup>(1)</sup></p>      <p>&nbsp;</p>      <p align="center"><sup>(1)</sup> ICEMS Grupo de Materiais e Engenharia de Superfícies    – Faculdade de Ciências e Tecnologia da Universidade de Coimbra – Rua Luís Reis    Santos, 3030-788 Coimbra, Portugal</p>      <p align="center"><a href="mailto:albano.cavaleiro@dem.uc.pt">albano.cavaleiro@dem.uc.pt</a></p>     <p align="center"><sup>(2)</sup> Escola Superior de Tecnologia e Gestão, Instituto    Politécnico da Guarda, Guarda, Portugal </p>       <p>&nbsp;</p>     <p>&nbsp;</p>      <p align="justify"><b>ABSTRACT: </b> W-C-S films were deposited either by a reactive    process in an Ar+CH<sub>4</sub> atmosphere or by co-sputtering WS<sub>2</sub>    and C targets. The films were characterized concerning their chemical composition    and mechanical properties. The results showed that the films, in both systems,    have similar properties. Co-sputtered films are amorphous, whereas in the reactive    process a gradual l oss of cristallinity is observed with the increase of C    content in the films. The hardness and the adhesion are similar for both systems.    The increase of C alloying to the films led to the improvement of both their    hardness and adhesion.</p>     ]]></body>
<body><![CDATA[<p align="justify">The tribological performance of the coatings was tested by    ball-on-disk. The films deposited by co-sputtering present better results than    the reactive deposited ones. With the increase of C content in these coatings    an increase of the wear resistance is observed, reaching in the best case a    wear coefficient of 3.1×10<sup>-16</sup> m<sup>3</sup>/N×m. In the films deposited    by reactive process, low wear coefficients can also be reached but no regular    trend with increasing C contents can be observed.</p>      <p align="justify"><b>Keywords</b>: Tungsten disulfide; WS<sub>2</sub>; Friction    coefficient; Wear coefficient; Self-lubricant</p>      <p>&nbsp;</p>     <p>&nbsp;</p>      <p>Texto completo disponível apenas em PDF.</p>     <p>Full text only available in PDF format.</p>      <p>&nbsp;</p>     <p>&nbsp;</p>      <p><b>References</b></p>      <!-- ref --><p>[1] I. L. Singer, S. Fayeulle, P. D. Ehni, Wear 195 (1996) 7-20&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;[&#160;<a href="javascript:void(0);" onclick="javascript: window.open('/scielo.php?script=sci_nlinks&ref=140740&pid=S0870-8312200600010000400001&lng=','','width=640,height=500,resizable=yes,scrollbars=1,menubar=yes,');">Links</a>&#160;]<!-- end-ref --><p>[2] T. Spalvins, Thin Solid Films, 96 (1982) 17-24</p>      <p>[3] P. J. John, S. V. Prasad, A. A. Voevodin, J. S. Zabinski, Wear, 219 (1998) 155-161</p>      <p>[4] A. A. Voevodin, J. P. O’Neill, J. S. Zabinski, Tribology Letters, 6 (1999) 75-78</p>      <p>[5] J. S. Zabinski, J. E. Florkey, S. D. Walck, J. E. Bultman, N. T. McDevitt, Surf. Coat.  Technol. 76-77 (1995) 400-406</p>      <p>[6] A. Nossa, A. Cavaleiro, Surf. Coat. Technol. 163-164 (2003) 552-560</p>      <p>[7] A. A. Voevodin, J. P. O’Neill, J. S. Zabinski, Surf. Coat. Technol. 116-119 (1999)  36-45</p>      <p>[8] A. Nossa, A. Cavaleiro, N. J. M. Carvalho, B. J. Kooi, J. Th. De Hosson, Thin Solid  Films, 484 (2005), 389-395</p>      <p>[9] A. K. Rai, R. S. Bhattacharya, J. S. Zabinski, K. Miyoshi, Surf. Coat. Technol. 92  (1997) 120-128</p>      <p>[10] M. Hirano, S. Miyake, Applied Physics Letters, 47 (7) October (1985) 683-685</p>      <p>[11] M. Regula, C. Ballif, M. Remskar, F. Lévy, Journal of Vacuum Science and Technology,  A 15(4), Jul/Aug (1997) 2323-2329</p>      ]]></body>
<body><![CDATA[<p>[12]  M. Evaristo, A. Nossa, A. Cavaleiro, Surf. Coat. Technol, 200 (2005), 1076-1079</p>      <p>[13] A. Nossa, A. Cavaleiro, J. Mater. Res. 19 (8) (2004) 2356-2365</p>      <p>[14] A. Nossa, A. Cavaleiro, Surf. Coat. Technol. 142-144 (2001) 984-991</p>      <p>[15] R. Gilmore, M. A. Baker, P. N. Gibson, W. Gissler, M. Stoiber, P. Losbichler, C.  Mitterer, Surf. Coat. Technol, 108-109 (1998) 345-351</p>      <p>[16] S. V. Prasad, J. S. Zabinski, Journal of Material Science Letters, 12 (1993),  1413-1415</p>       ]]></body><back>
<ref-list>
<ref id="B1">
<nlm-citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname><![CDATA[Singer]]></surname>
<given-names><![CDATA[I. L.]]></given-names>
</name>
<name>
<surname><![CDATA[Fayeulle]]></surname>
<given-names><![CDATA[S.]]></given-names>
</name>
<name>
<surname><![CDATA[Ehni]]></surname>
<given-names><![CDATA[P. D.]]></given-names>
</name>
</person-group>
<source><![CDATA[Wear]]></source>
<year>1996</year>
<volume>195</volume>
<page-range>7-20</page-range></nlm-citation>
</ref>
</ref-list>
</back>
</article>
