<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>0872-1904</journal-id>
<journal-title><![CDATA[Portugaliae Electrochimica Acta]]></journal-title>
<abbrev-journal-title><![CDATA[Port. Electrochim. Acta]]></abbrev-journal-title>
<issn>0872-1904</issn>
<publisher>
<publisher-name><![CDATA[Sociedade Portuguesa de Electroquímica]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S0872-19042006000200011</article-id>
<title-group>
<article-title xml:lang="en"><![CDATA[Activity coefficients of potassium chloride in aqueous solutions of potassium chloride and potassium phthalate]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Marques]]></surname>
<given-names><![CDATA[A.]]></given-names>
</name>
<xref ref-type="aff" rid="A01"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Ferra]]></surname>
<given-names><![CDATA[M.I.A.]]></given-names>
</name>
<xref ref-type="aff" rid="A01"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Bandeira]]></surname>
<given-names><![CDATA[M.H.]]></given-names>
</name>
<xref ref-type="aff" rid="A01"/>
</contrib>
</contrib-group>
<aff id="A01">
<institution><![CDATA[,Universidade da Beira-Interior Departamento de Química ]]></institution>
<addr-line><![CDATA[Covilhã ]]></addr-line>
<country>Portugal</country>
</aff>
<pub-date pub-type="pub">
<day>00</day>
<month>00</month>
<year>2006</year>
</pub-date>
<pub-date pub-type="epub">
<day>00</day>
<month>00</month>
<year>2006</year>
</pub-date>
<volume>24</volume>
<numero>2</numero>
<fpage>295</fpage>
<lpage>303</lpage>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_arttext&amp;pid=S0872-19042006000200011&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_abstract&amp;pid=S0872-19042006000200011&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_pdf&amp;pid=S0872-19042006000200011&amp;lng=en&amp;nrm=iso"></self-uri><abstract abstract-type="short" xml:lang="en"><p><![CDATA[Mean activity coefficients of potassium chloride were determined in aqueous solutions of potassium chloride and potassium phthalate, in the temperature range 10-50 ºC and ionic strength range 0.05-4 mol kg-1, from potentiometric measurements on a galvanic cell without liquid junction. By processing the results using the Pitzer model, interaction parameters for potassium phthalate were calculated as well as their temperature dependence.]]></p></abstract>
<kwd-group>
<kwd lng="en"><![CDATA[activity coefficients]]></kwd>
<kwd lng="en"><![CDATA[potassium phthalate]]></kwd>
<kwd lng="en"><![CDATA[Pitzer equations]]></kwd>
</kwd-group>
</article-meta>
</front><body><![CDATA[ <p align="center"><b>Activity coefficients of potassium chloride in aqueous solutions of </b></p>     <p align="center"><b>potassium chloride and potassium phthalate</b></p>     <p align="center">&nbsp;</p>     <p align="center"><b>&nbsp;</b><b>A. Marques</b><b>,<i><a href="#1">*</a></i><a name="top1"></a>    M.I.A. Ferra, M.H. Bandeira</b></p>      <p align="center"><i >Dep</i><i >. Química, Univ. Beira-Interior, 6201-001 Covilhã,    Portugal</i></p>     <p><i ></i></p>      <p>&nbsp;</p>      <p>&nbsp;</p>      <p><b>Abstract</b></p>      <p align="justify">Mean activity coefficients of potassium chloride were determined    in aqueous solutions of potassium chloride and potassium phthalate, in the temperature    range 10-50 ºC and ionic strength range 0.05-4 mol kg<sup>-1</sup>, from potentiometric    measurements on a galvanic cell without liquid junction. By processing the results    using the Pitzer model, interaction parameters for potassium phthalate were    calculated as well as their temperature dependence.</p>     ]]></body>
<body><![CDATA[<p align="justify"><b ><i>Keywords</i></b><b><i >:</i> </b>activity coefficients,    potassium phthalate, Pitzer equations.</p>      <p>&nbsp;</p>      <p>Texto disponível em PDF</p>      <p>Full text only in PDF format</p>      <p>&nbsp;</p>      <p><b>References</b></p>      <!-- ref --><p >1. R.P. Buck, S. Rondinini, A.K. Covington, F.G.K. Baucke, C.M.A. Brett, M.F. Camões, M.J.T. Milton, T. Mussini, R. Naumann, K.W. Pratt, P. Spitzer, G.S. Wilson, <i >Pure</i><i> Appl. Chem</i>. 74, 11 (2002<b>)</b> 2169-2200.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;[&#160;<a href="javascript:void(0);" onclick="javascript: window.open('/scielo.php?script=sci_nlinks&ref=000019&pid=S0872-1904200600020001100001&lng=','','width=640,height=500,resizable=yes,scrollbars=1,menubar=yes,');">Links</a>&#160;]<!-- end-ref --><p>2. R.G. Bates, E.A. Guggenheim, <i >Pure</i><i > Appl. Chem</i>. 1 (1960) 163.</p>      <p>3. K.S. Pitzer, <i >J. Phys. Chem</i>. 77 (<i >1973</i>) 268.</p>      <p>4. A.K. Covington, M.I.A. Ferra, <i>J. Sol. Chem</i>. 23 (1994) 1.</p>      ]]></body>
<body><![CDATA[<p>5. K.S. Pitzer, “Ion Interaction Approach: Theory and Data Correlation”, in <i >Activity Coefficients in Electrolyte Solutions</i>, 2<sup>nd</sup> ed., K.S. Pitzer, Ed., CRC Press, Boca Raton, Florida, U. S. A.<b> </b>1991.</p>      <p >6. R.G. Bates, <i>Determination of pH. Theory and Pratctice</i>, 2<sup>nd</sup> ed., John Wiley &amp; Sons, Inc., New York, U. S. A.,<b> </b>1973.</p>      <p >7. R.A. Robinson, R.H. Stokes, <i>Electrolyte Solutions</i>, 2.<sup>nd.</sup> ed., (revised), Butterworth &amp; Co, London, 1970.</p>      <p >8. C.Y. Chan, Y.W. Eng, K.S. Eu, <i>J. Chem. Eng. Data</i> 40 (1995) 685.</p>      <p>9. J.I. Partanen, P.O. Minkkinen, <i>J. Chem. Eng. </i><i>Data </i>42 (1997) 805.</p>      <p>10. W.J. Hamer, G.D. Pinching, S.F. Acree, <i>J. Res. Natl. Bur. Stand. </i>35    (1945) 539.</p>      <p>11. W.J. Hamer, S.F. Acree, <i>J. Res. Natl. Bur. Stand</i>. 35 (1945) 381.</p>      <p >12. A.J.G. Mendonça, P.M. Juusola, <i>Fluid Phase Equilibria</i> 231 (2005)    114.</p>      <p>&nbsp;</p>      <p><a href="#top1">*</a><a name="1"></a>Corresponding author. E-mail address:    <a href="mailto:ammmba@ubi.pt">ammmba@ubi.pt</a> </p>     ]]></body>
<body><![CDATA[<p>&nbsp;</p>        ]]></body><back>
<ref-list>
<ref id="B1">
<nlm-citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname><![CDATA[Buck]]></surname>
<given-names><![CDATA[R.P.]]></given-names>
</name>
<name>
<surname><![CDATA[Rondinini]]></surname>
<given-names><![CDATA[S.]]></given-names>
</name>
<name>
<surname><![CDATA[Covington]]></surname>
<given-names><![CDATA[A.K.]]></given-names>
</name>
<name>
<surname><![CDATA[Baucke]]></surname>
<given-names><![CDATA[F.G.K.]]></given-names>
</name>
<name>
<surname><![CDATA[Brett]]></surname>
<given-names><![CDATA[C.M.A.]]></given-names>
</name>
<name>
<surname><![CDATA[Camões]]></surname>
<given-names><![CDATA[M.F.]]></given-names>
</name>
<name>
<surname><![CDATA[Milton]]></surname>
<given-names><![CDATA[M.J.T.]]></given-names>
</name>
<name>
<surname><![CDATA[Mussini]]></surname>
<given-names><![CDATA[T.]]></given-names>
</name>
<name>
<surname><![CDATA[Naumann]]></surname>
<given-names><![CDATA[R.]]></given-names>
</name>
<name>
<surname><![CDATA[Pratt]]></surname>
<given-names><![CDATA[K.W.]]></given-names>
</name>
<name>
<surname><![CDATA[Spitzer]]></surname>
<given-names><![CDATA[P.]]></given-names>
</name>
<name>
<surname><![CDATA[Wilson]]></surname>
<given-names><![CDATA[G.S.]]></given-names>
</name>
</person-group>
<source><![CDATA[Pure Appl. Chem.]]></source>
<year>2002</year>
<volume>11</volume>
<numero>74</numero>
<issue>74</issue>
<page-range>2169-2200</page-range></nlm-citation>
</ref>
</ref-list>
</back>
</article>
