<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>0872-1904</journal-id>
<journal-title><![CDATA[Portugaliae Electrochimica Acta]]></journal-title>
<abbrev-journal-title><![CDATA[Port. Electrochim. Acta]]></abbrev-journal-title>
<issn>0872-1904</issn>
<publisher>
<publisher-name><![CDATA[Sociedade Portuguesa de Electroquímica]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S0872-19042009000500004</article-id>
<title-group>
<article-title xml:lang="en"><![CDATA[Stainless Steel Electrodeposited with Zinc is not Good for Storing Thiourea Solution]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Rajendran]]></surname>
<given-names><![CDATA[S.]]></given-names>
</name>
<xref ref-type="aff" rid="A01"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Brigita]]></surname>
<given-names><![CDATA[V. Agnes]]></given-names>
</name>
<xref ref-type="aff" rid="A02"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Manivannan]]></surname>
<given-names><![CDATA[J.]]></given-names>
</name>
<xref ref-type="aff" rid="A03"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Jeyasundari]]></surname>
<given-names><![CDATA[J.]]></given-names>
</name>
<xref ref-type="aff" rid="A04"/>
</contrib>
</contrib-group>
<aff id="A01">
<institution><![CDATA[,G.T.N Arts College Department of Chemistry Corrosion Research Centre]]></institution>
<addr-line><![CDATA[Dindigul Tamil Nadu]]></addr-line>
<country>India</country>
</aff>
<aff id="A02">
<institution><![CDATA[,Madurai Kamaraj University RVS College Of Education ]]></institution>
<addr-line><![CDATA[Dindigul Tamil Nadu]]></addr-line>
<country>India</country>
</aff>
<aff id="A03">
<institution><![CDATA[,Chettinad College of Engineering and Technology Department of Chemistry ]]></institution>
<addr-line><![CDATA[Karur Tamil Nadu]]></addr-line>
<country>India</country>
</aff>
<aff id="A04">
<institution><![CDATA[,SVN College Department of Chemistry ]]></institution>
<addr-line><![CDATA[Madurai ]]></addr-line>
<country>India</country>
</aff>
<pub-date pub-type="pub">
<day>00</day>
<month>00</month>
<year>2009</year>
</pub-date>
<pub-date pub-type="epub">
<day>00</day>
<month>00</month>
<year>2009</year>
</pub-date>
<volume>27</volume>
<numero>5</numero>
<fpage>555</fpage>
<lpage>564</lpage>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_arttext&amp;pid=S0872-19042009000500004&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_abstract&amp;pid=S0872-19042009000500004&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_pdf&amp;pid=S0872-19042009000500004&amp;lng=en&amp;nrm=iso"></self-uri><abstract abstract-type="short" xml:lang="en"><p><![CDATA[The use of stainless steel 304(SS) tanks to deposit thiourea in industry has been evaluated by studying the corrosion behaviour in 1% thiourea solution, before and after zinc plating.Weight loss method, 1% copper sulphate test, polarization study and AC impedance spectra have been used.The corrosion resistance of SS decreased when zinc was used for electrodeposition.Hence SS vessels electroplated with zinc should not be used to store thiourea solution, in industry.]]></p></abstract>
<kwd-group>
<kwd lng="en"><![CDATA[stainless steel]]></kwd>
<kwd lng="en"><![CDATA[zinc plating]]></kwd>
<kwd lng="en"><![CDATA[corrosion]]></kwd>
<kwd lng="en"><![CDATA[thiourea]]></kwd>
<kwd lng="en"><![CDATA[case study]]></kwd>
</kwd-group>
</article-meta>
</front><body><![CDATA[ <P align="center"><B>Stainless Steel Electrodeposited with Zinc is not Good for    Storing Thiourea Solution</B></P>     <P align="center"><B>S. Rajendran,</b> <sup>1, <a href="#1">*</a></sup><b><a name="top1"></a>    V. Agnes Brigita,</b> <sup>2</sup><b> J. Manivannan,</b><sup>3</sup><b>J. Jeyasundari    </B><sup>4</sup></P>     <P align="center" ><I ><sup>1</sup> Corrosion Research Centre, Post Graduate and    Research, Department of Chemistry, G.T.N Arts College, Dindigul -624005, Tamil    Nadu, India.</I></P>     <P align="center"><i><sup>2</sup>RVS College of Education, RVS Nagar, Dindigul    – 624005, Tamil Nadu, India</I></P>     <P align="center"><I ><SUP>3 </SUP>Department of Chemistry, Chettinad College    of Engineering and Technology, Karur-639114, Tamil Nadu, India.</I></P>     <P align="center"><I ><sup>4</SUP>Department of Chemistry, SVN College, Madurai,    India </I></P>     <P align="center">&nbsp;</P>     <P align="center">Received 14 February 2009; accepted 24 September 2009</P>     <P align="center">&nbsp;</P>     <P><B>Abstract</B></P>     ]]></body>
<body><![CDATA[<P>The use of stainless steel 304(SS) tanks to  deposit thiourea in industry has been evaluated by studying the corrosion  behaviour in 1% thiourea solution, before and after zinc plating.Weight loss method, 1% copper sulphate  test, polarization study and AC impedance spectra have been used.The corrosion resistance of SS decreased  when zinc was used for electrodeposition.Hence SS vessels electroplated with zinc should not be used to store  thiourea solution, in industry.</P>     <P><B><I>Keywords</i></B>: stainless steel, zinc plating, corrosion, thiourea,    case study.</P>     <P>&nbsp;</P>     <P>Full text only in PDF format</p>     <p>Texto dispon&iacute;vel em PDF</p>     <p>&nbsp;</p>     <P><B>References </B></P>     <P >1. D.A. Schario, M.L.  Klingenberg, E.W. Brooman, Abstracts of the 190th Meeting of the Electrochem.  Soc., Vol. 96-2, No.309, The Electrochem. Soc., Pennington, NJ, 1996, p. 398.</P>     <!-- ref --><P>2. M. Pushpavanaman, <I>Bull. Electrochem.</I> 16 (2000)  559.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;[&#160;<a href="javascript:void(0);" onclick="javascript: window.open('/scielo.php?script=sci_nlinks&ref=000021&pid=S0872-1904200900050000400001&lng=','','width=640,height=500,resizable=yes,scrollbars=1,menubar=yes,');">Links</a>&#160;]<!-- end-ref --><P>3. O.A. Ashiru, J.  Shiroko, <I >Appl. Surf. Science</I> 103  (1996) 159.</P>     ]]></body>
<body><![CDATA[<P>4. V.S. Vasantha, M.  Pushpavanam, P. Kamaraj, V.S. Muralidharan, <I  >Trans. IMF</I> 74 (1996)  28.</P>     <P >5. St. Vitkova, V.  Ivanova, G. Raichevsky, <I >Surf. Coat.  Tech</I>. 82 (1996) 226.</P>     <P >6. M. An, Y. Zhang, J.  Zhang, Z. Yang, Z. Tu, <I >Plating Surf.  Finishing</I> 86 (1999) 130.</P>     <P >7. L. Szira´ki, A´.  Czira´ki, Z. Ve´rtesy, L. Kiss, V. Ivanova, G. Raichevski, S. Vitkova, Ts.  Marinova, <I >J. Appl. Electrochem.</I> 29  (1999) 927.</P>     <P >8. S.M. Abdel-Wahab, E.  Mohamed, S.M. Rashwan, <I >Metall.</I>  54  (2000) 268.</P>     <P>9. K. Wang, H.W.  Pickering, K.G. Weill, <I >Electrochim.  Acta</I> 46 (2001) 3835.</P>     <P>10.  E. Guaus, J. Torrent, <I  >J. Electroanal. Chem.</I> 549 (2003)  25.</P>     <P>11.  K. Wang-Lung, Li-Min Sun,<I  > J. Mater. Res.</I>  18 (2003) 2203.</P>     <P >12.  A. Brenner, Electrodeposition of  Alloys: Principles and Practice, Vol. II, Academic Press, New York, 1963, p.  30.</P>     <P >13. E. Guaus, J. Torrent-Burgués, <I  >Journal of Electroanalytical Chemistry,  </I>575 (2005) 301</P>     ]]></body>
<body><![CDATA[<P >14. <a href="http://www.finishing.com/160/63.shtml" target="_blank">http://www.finishing.com/160/63.shtml</a>  </P>     <P >15. <a href="http://www.finishing.com/380/35.shtml" target="_blank">http://www.finishing.com/380/35.shtml</a>  </P>     <P >16.  G. Wranglen, Introduction to  Corrosion and Protection of Metals, Chapman and Hall, London, 1985,  p.236.</P>     <P >17. Clyde E. Williams and E. Anderson, <I >The  Journal of Industrial and Engineering Chemistry</I>, Nov. 1922,  p.1057.</P>     <P >18. <a href="http://en.wikipedia.org/wiki/copper" target="_blank">http://en.wikipedia.org/wiki/copper</a></P>     <P >19. M.G. Fontana, <I  >Corrosion Engineering</I>, Tata McGraw-Hill Publishing Company Ltd., New Delhi,    2006, p.43.</P>     <P >&nbsp;</P>      <P><sup><a name="1"></a><a href="#top1">*</a></sup>Corresponding author. E-mail    address: <a href="mailto:srmjoany@sify.com.">srmjoany@sify.com.</a> </P>      ]]></body><back>
<ref-list>
<ref id="B1">
<nlm-citation citation-type="journal">
<person-group person-group-type="author">
<name>
<surname><![CDATA[Pushpavanaman]]></surname>
<given-names><![CDATA[M.]]></given-names>
</name>
</person-group>
<source><![CDATA[Bull. Electrochem.]]></source>
<year>2000</year>
<volume>16</volume>
<page-range>559</page-range></nlm-citation>
</ref>
</ref-list>
</back>
</article>
