<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>0872-1904</journal-id>
<journal-title><![CDATA[Portugaliae Electrochimica Acta]]></journal-title>
<abbrev-journal-title><![CDATA[Port. Electrochim. Acta]]></abbrev-journal-title>
<issn>0872-1904</issn>
<publisher>
<publisher-name><![CDATA[Sociedade Portuguesa de Electroquímica]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S0872-19042009000500006</article-id>
<title-group>
<article-title xml:lang="en"><![CDATA[Ethanol Extract of Phyllanthus Amarus as a Green Inhibitor for the Corrosion of Mild Steel in H2SO4]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Eddy]]></surname>
<given-names><![CDATA[N. O.]]></given-names>
</name>
<xref ref-type="aff" rid="A01"/>
</contrib>
</contrib-group>
<aff id="A01">
<institution><![CDATA[,Ahmadu Bello University Department of Chemistry ]]></institution>
<addr-line><![CDATA[Zaria Kaduna]]></addr-line>
<country>Nigeria</country>
</aff>
<pub-date pub-type="pub">
<day>00</day>
<month>00</month>
<year>2009</year>
</pub-date>
<pub-date pub-type="epub">
<day>00</day>
<month>00</month>
<year>2009</year>
</pub-date>
<volume>27</volume>
<numero>5</numero>
<fpage>579</fpage>
<lpage>589</lpage>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_arttext&amp;pid=S0872-19042009000500006&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_abstract&amp;pid=S0872-19042009000500006&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_pdf&amp;pid=S0872-19042009000500006&amp;lng=en&amp;nrm=iso"></self-uri><abstract abstract-type="short" xml:lang="en"><p><![CDATA[Inhibitive and adsorption properties of ethanol extract of Phyllanthus amarus for the corrosion of mild steel in H2SO4 were investigated using gravimetric, thermometric and gasometric methods. Ethanol extract of Phyllanthus amarus leaves is a good adsorption inhibitor for the corrosion of mild steel in H2SO4. Thermodynamic consideration indicates that the adsorption of the extract is exothermic and spontaneous. Also, the adsorption characteristic of the inhibitor is consistent with the assumptions of Langmuir adsorption isotherm. From the results and findings of the study, a physical adsorption mechanism is proposed for the adsorption of ethanol extract of Phyllanthus amarus on mild steel surface. The inhibition potentials of ethanol extract of Phyllanthus amarus leaves are enhanced by its phytochemical constituents.]]></p></abstract>
<kwd-group>
<kwd lng="en"><![CDATA[corrosion]]></kwd>
<kwd lng="en"><![CDATA[inhibition]]></kwd>
<kwd lng="en"><![CDATA[Phyllanthus amarus]]></kwd>
</kwd-group>
</article-meta>
</front><body><![CDATA[ <P align="center"><B >Ethanol Extract of <I>Phyllanthus Amarus</I> as a Green    Inhibitor for the Corrosion of Mild Steel in H<SUB>2</SUB>SO<SUB>4</SUB></B></P>     <P align="center"><B>N. O. Eddy <sup><a href="#1">*</a><a name="top1"></a></sup></B></P>     <P align="center"><i>Department of Chemistry Ahmadu Bello University Zaria, Kaduna    State, Nigeria</I></P>     <P align="center">&nbsp;</P>     <P align="center">Received 23 February 2009; accepted 23 October 2009</P>     <P align="center">&nbsp;</P>     <P><B >Abstract</B></P>     <P>Inhibitive and adsorption  properties of ethanol extract of Phyllanthus amarus for the corrosion of mild  steel in H<SUB>2</SUB>SO<SUB>4</SUB> were investigated using gravimetric,  thermometric and gasometric methods. Ethanol extract of Phyllanthus amarus  leaves is a good adsorption inhibitor for the corrosion of mild steel in  H<SUB>2</SUB>SO<SUB>4</SUB>. Thermodynamic consideration indicates that the  adsorption of the extract is exothermic and spontaneous. Also, the adsorption  characteristic of the inhibitor is consistent with the assumptions of Langmuir  adsorption isotherm. From the results and findings of the study, a physical  adsorption mechanism is proposed for the adsorption of ethanol extract of <I  >Phyllanthus amarus</I> on mild steel  surface. The inhibition potentials of ethanol extract of <I  >Phyllanthus amarus</I> leaves are enhanced  by its phytochemical constituents.</P>     <P ><B><I>Keywords</I></B>: corrosion, inhibition, <I >Phyllanthus amarus.</I></P>     <P >&nbsp;</P>     ]]></body>
<body><![CDATA[<P>Full text only in PDF format</p>     <p>Texto dispon&iacute;vel em PDF</p>     <p>&nbsp;</p>     <P ><B >References</B></P>     <P >1. N.O. Eddy, P.  Ekwumemgbo and S.A. Odoemelam, <i>Inter. Journal of Physical Sciences.  </I>3(11) (2008) 1.</P>     <P >2. N.O. Eddy and  S.A. Odoemelam, <i>Inter. J. of Pure and Applied Chem</I>. 3(4)  (2008)1.</P>     <P>3. N.O. Eddy, S.A.  Odoemelam and A.O. Odiongenyi, <i>J. Appl.  Electrochem</I>. 39(6) (2009) 849 - 857. </P>     <P>4. N.O. Eddy, S.A. Odoemelam and N.W. Akpanudoh,  <i>J. Chem. Technol.</i> 4 (2008) 1-10.</P>     <P>5. M. Abdallah, <i>Corrosion Sc. </I>44 (2002)  717.</P>     <P>6. S. Acharya and  S.N. Upadhyay, <i>Trans. Indian Inst. Met.  </I> 57(3)  (2004) 297.</P>     ]]></body>
<body><![CDATA[<P>7. E.E. Ebenso, <i>Mater. Chem. Phys</I>. 79 (2003)  58.</P>     <P >8. A.Y. El-Etre, M.  Abdallah and Z.E. El-Tantawy,  <i>Corrosion Science</i> 47(2) (2005) 385.</P>     <P >9. L. Anauda, R.A.  Sathiyanathan, S.B. Maruthamuthu, M.C. Selvanayagam, S.B. Mohanan and N.B.  Palaniswamy, <I>Indian J. Chem. Tech</I>. 12(3) (2005) 356.  </P>     <P >10. N.O. Eddy and E.E. Ebenso, <i>African J. Pure Applied Chem</I>. 2(6)  (2008) 1.</P>     <P>11. M.A. Bendahou, M.B.E.  Benadellah and B.B. Hammouti, <i>Pigment and  Resin Technol</I>.35 (2006)  95.</P>     <P >12. A. Bouyanzer and B. Hammouti,  <i>Pigment and Resin Tech</I>. 33 (2004)  287.</P>     <P>13. A. Chetounani, B. Hammouti,  and M. Benkaddour,<i>Pigment and Resin  Tech.</I> 33 (2004) 26.</P>     <!-- ref --><P >14. E.E. Ebenso, N.O. Eddy and  A.O. Odiongenyi, <I>Portugaliae Electrochimica Acta</I> 27(1) (2009)  13.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;[&#160;<a href="javascript:void(0);" onclick="javascript: window.open('/scielo.php?script=sci_nlinks&ref=000030&pid=S0872-1904200900050000600001&lng=','','width=640,height=500,resizable=yes,scrollbars=1,menubar=yes,');">Links</a>&#160;]<!-- end-ref --><P>15. N.O. Eddy and A.S. Ekop, <i>Asian J. Chem</I>. 19(3) (2007) 1825. </P>     <!-- ref --><P >16. A.O. Odiongenyi, S.A.  Odoemelam and N.O. Eddy, <I>Portugaliae Electrochimica Acta</I> 17(1) (2009) 33.  &nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;[&#160;<a href="javascript:void(0);" onclick="javascript: window.open('/scielo.php?script=sci_nlinks&ref=000032&pid=S0872-1904200900050000600002&lng=','','width=640,height=500,resizable=yes,scrollbars=1,menubar=yes,');">Links</a>&#160;]<!-- end-ref --><P>17. N.O. Eddy, <i>Inhibition  of corrosion of mild steel by some antibiotics,</i> Ph.D Thesis, University of  Calabar, (2007).</P>     <P>18. S.A. Odoemelam  and N.O. Eddy, <i>J. Surface Sci.  Technol. </I>24(1-2) (2008) 1.  </P>     <P >19. E.E. Ebenso and E.E. Oguzie,  <i>Mat. Letters</I> 59 (2005)  2163.</P>     <P>20. N.O. Eddy, S.A. Odoemelam and  A.J. Mbaba, <i>Afri</I>. <i>J. Pure Applied Chem.</I> 2(12) (2008)  132.</P>     <P>21. N.O. Eddy, U.J. Ibok, E.E. Ebenso, A.E. Nemr and E.H. El Ashry, <i>J. Molecular    Modeling. </I>DOI 10.1007/s00894-009-0472-7 (2009)</P>     <P>&nbsp;</P>     <P><sup><a name="1"></a><a href="#top1">*</a></sup>Corresponding author. E-mail    address: <a href="mailto:nabukeddy@yahoo.com">nabukeddy@yahoo.com</a>       ]]></body><back>
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<source><![CDATA[Portugaliae Electrochimica Acta]]></source>
<year>2009</year>
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