<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>0872-1904</journal-id>
<journal-title><![CDATA[Portugaliae Electrochimica Acta]]></journal-title>
<abbrev-journal-title><![CDATA[Port. Electrochim. Acta]]></abbrev-journal-title>
<issn>0872-1904</issn>
<publisher>
<publisher-name><![CDATA[Sociedade Portuguesa de Electroquímica]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S0872-19042021000600415</article-id>
<article-id pub-id-type="doi">10.4152/pea.2021390603</article-id>
<title-group>
<article-title xml:lang="en"><![CDATA[Atomic Absorption Spectroscopy Reveals Anomalous Transfer of Heavy Metal across a Water/1,2-DCE Interface]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Silver]]></surname>
<given-names><![CDATA[B. R.]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
</contrib-group>
<aff id="Af1">
<institution><![CDATA[,J. Heyrovsky Institute of Physical Chemistry of the CAS Biophysical Chemistry Department ]]></institution>
<addr-line><![CDATA[Prague ]]></addr-line>
<country>Czech Republic</country>
</aff>
<pub-date pub-type="pub">
<day>30</day>
<month>12</month>
<year>2021</year>
</pub-date>
<pub-date pub-type="epub">
<day>30</day>
<month>12</month>
<year>2021</year>
</pub-date>
<volume>39</volume>
<numero>6</numero>
<fpage>415</fpage>
<lpage>420</lpage>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_arttext&amp;pid=S0872-19042021000600415&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_abstract&amp;pid=S0872-19042021000600415&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_pdf&amp;pid=S0872-19042021000600415&amp;lng=en&amp;nrm=iso"></self-uri><abstract abstract-type="short" xml:lang="en"><p><![CDATA[Abstract Atomic absorption spectroscopy (AAS) of samples taken from the organic phase of a water/1,2-dichloroethane (1,2-DCE) interfacial electrochemical cell, rendered non-polarizable by the tetraphenylarsonium common-ion, revealed significant transfer of heavy metal from the aqueous phase. Heavy metal concentration found within 1,2-DCE cannot be explained via ion pair formation between the metallic species and the common-ion, nor by ion pair formation between the metallic species and the hydrophobic anion of the organic phase. Results suggest that metal may have been anomalously transferred into 1,2-DCE within water-in-oil droplets formed by spontaneous emulsification of the interfacial region.]]></p></abstract>
<kwd-group>
<kwd lng="en"><![CDATA[liquid/liquid]]></kwd>
<kwd lng="en"><![CDATA[extraction]]></kwd>
<kwd lng="en"><![CDATA[metal]]></kwd>
<kwd lng="en"><![CDATA[non-polarizable]]></kwd>
<kwd lng="en"><![CDATA[ITIES (interface between two immiscible electrolyte solutions)]]></kwd>
</kwd-group>
</article-meta>
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