<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>0872-1904</journal-id>
<journal-title><![CDATA[Portugaliae Electrochimica Acta]]></journal-title>
<abbrev-journal-title><![CDATA[Port. Electrochim. Acta]]></abbrev-journal-title>
<issn>0872-1904</issn>
<publisher>
<publisher-name><![CDATA[Sociedade Portuguesa de Electroquímica]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S0872-19042023000200081</article-id>
<article-id pub-id-type="doi">10.4152/pea.2023410201</article-id>
<title-group>
<article-title xml:lang="en"><![CDATA[Experimental Evaluation and Theoretical Study of Imidazolium and Benzimidazolium. Derivatives as Corrosion Inhibitors of Mild Steel in a 0.5 M H2SO4 Solution]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Said]]></surname>
<given-names><![CDATA[Mohamed Elhadi]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
<xref ref-type="aff" rid="Aaf"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Bouchouit]]></surname>
<given-names><![CDATA[Mehdi]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Zaiter]]></surname>
<given-names><![CDATA[Abdellah]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
<xref ref-type="aff" rid="Aaf"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Mezhoud]]></surname>
<given-names><![CDATA[Bilel]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Bouacida]]></surname>
<given-names><![CDATA[Sofiane]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Chibani]]></surname>
<given-names><![CDATA[Aissa]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Bouraiou]]></surname>
<given-names><![CDATA[Abdelmalek]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
</contrib-group>
<aff id="Af1">
<institution><![CDATA[,University of Frères Mentouri Unit for Environmental Chemistry and Molecular Structural Research ]]></institution>
<addr-line><![CDATA[Constantine ]]></addr-line>
<country>Algeria</country>
</aff>
<aff id="Af2">
<institution><![CDATA[,University Mohamed Boudief M&#8217;ila Faculty of Technology ]]></institution>
<addr-line><![CDATA[ ]]></addr-line>
<country>Algeria</country>
</aff>
<aff id="Af3">
<institution><![CDATA[,University of Larbi Ben M&#8217;Hidi Laboratory of Applied Chemistry and Matherials Tecnhology ]]></institution>
<addr-line><![CDATA[Oum El Bouaghi ]]></addr-line>
<country>Algeria</country>
</aff>
<pub-date pub-type="pub">
<day>00</day>
<month>04</month>
<year>2023</year>
</pub-date>
<pub-date pub-type="epub">
<day>00</day>
<month>04</month>
<year>2023</year>
</pub-date>
<volume>41</volume>
<numero>2</numero>
<fpage>81</fpage>
<lpage>101</lpage>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_arttext&amp;pid=S0872-19042023000200081&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_abstract&amp;pid=S0872-19042023000200081&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://scielo.pt/scielo.php?script=sci_pdf&amp;pid=S0872-19042023000200081&amp;lng=en&amp;nrm=iso"></self-uri><abstract abstract-type="short" xml:lang="en"><p><![CDATA[Abstract (dimOHmIm)+,I- and (dimOHmBim)+,I- were investigated as a corrosion inhibitors for MS in 0.5 M H2SO4 using gravimetric, PDP and EIS techniques. Polarization curves revealed that both compounds acted as mixed-type inhibitors, and that corrosion IE% increased with their higher concentrations. The adsorption of both inhibitors onto the MS surface obeyed Langmuir&#8217;s isotherm. The compound II showed a higher corrosion IE% than that of I. The quantum chemical calculations were applied to investigate the relationship between the two azolium salts derivatives electronic properties and their corrosion IE%.]]></p></abstract>
<kwd-group>
<kwd lng="en"><![CDATA[imidazolium and benzimidazolium salts]]></kwd>
<kwd lng="en"><![CDATA[MS]]></kwd>
<kwd lng="en"><![CDATA[polarization]]></kwd>
<kwd lng="en"><![CDATA[EIS]]></kwd>
<kwd lng="en"><![CDATA[WL and corrosion inhibition]]></kwd>
</kwd-group>
</article-meta>
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